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Tailored Metal Catalysts [Hardcover]

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  • Category: Books (Science)
  • ISBN-10:  9027718660
  • ISBN-10:  9027718660
  • ISBN-13:  9789027718662
  • ISBN-13:  9789027718662
  • Publisher:  Springer
  • Publisher:  Springer
  • Pages:  333
  • Pages:  333
  • Binding:  Hardcover
  • Binding:  Hardcover
  • Pub Date:  01-Feb-1985
  • Pub Date:  01-Feb-1985
  • Item ID: 100993500
  • List Price: $279.99
  • Seller: ShopSpell
  • Ships in: 2 business days
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  • Delivery by: Jul 28 to Jul 30
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Inorganic Oxide-attached Metal Catalysts.- 1. Introduction.- 2. General Features of Homogeneous and Heterogeneous Catalysts.- 3. General Aspects of the Development of Attached Metal Catalysts.- 3.1. First Generation Attached Catalysts.- 3.2. Second Generation Attached Catalysts.- 3.3. Third Generation Attached Catalysts.- 4. Physical Techniques for the Characterization of Surface-attached Species.- 5. Polymers and Inorganic Oxides as Supports.- 6. Surface Hydroxyl Groups on Inorganic Oxides.- 6.1. Silica.- 6.2. Alumina.- 6.3. Silicaalumina.- 6.4. Zeolites.- 6.5. Titania.- 6.6. Other Inorganic Oxides.- 7. The Functionalization of Inorganic Oxide Surfaces.- 7.1. Silica.- 7.2. Alumina and Zeolites.- 7.3. Stannic Oxide and Carbon.- 8. Attached Metal Complex Catalysts.- 8.1. Metal Complexes Attached via Functional Ligands.- 8.2. Transition Metal Complexes Attached Directly to Inorganic Oxide Surfaces.- 9. Tailored Metal Catalysts.- 9.1. Multistep Attached Metal Catalysts.- 9.2. Transition Metal Hydride Catalysts.- 9.3. Attached Metal Oxide Catalysts.- 9.3.1. Surface Molybdenum Monomers.- 9.3.2. Surface Molybdenum Dimers.- 9.3.3. Oriented Mo03 Phases on Graphite.- 9.3.4. Surface Chromium Monomers and Dimers.- 9.3.5. Two-dimensional Surface CrIII Phase Attached onto SiO2.- 9.3.6. Attached Tungsten Monomers.- 9.3.7. Surface Cobalt Species.- 10. Concluding Remarks.- References.- Polymer-attached Catalysts.- 1. Introduction.- 2. Polymer-anchored Catalysts.- 2.1. Preparation and Characterization.- 2.2. The Influence of the Polymer Matrix on Catalysis.- 2.2.1. Isolation of Active Sites.- 2.2.2. Promotion of Coordinative Unsaturation.- 2.2.3. Concentration of the Ligand.- 2.2.4. Stabilization of Catalysts.- 2.2.5. Effect of Substrate Size and Shape on Selectivity.- 2.3. Effect of the Polymer Field.- 2.3.1. Hydrophobic Field.- 2.3.2. Electrostatic Field.- 2.3.3. Asymmetric Field.- 2.4. Multifunctional Catalysts.- 2.4.1. Cooperative Catalysis.- 2.4.2. Multistep Catalysis.l'

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