Thermal Decomposition and Combustion of Explosives and Propellants [Hardcover]

This unique book investigates the synthesis, kinetics, and thermal decomposition properties and processing of energy-producing materials used in propellants, explosives, pyrotechnic, and gas-generating compositions.

Thermal Decomposition and Combustion of Explosives and Propellants provides several mechanisms and stages for the thermal decomposition and combustion reactions of most flammable compounds and their mixtures, such asaliphatic and aromatic nitrocompounds, nitramines, nitroesters, organic azides, furazanes, tetrazols, difluoroamines, polynitrous heterocycles, and onium salts. The authors examine the classic problem of the dependence of explosive activity on molecular structure, using applications to predict the stability, compatibility, and the stabilization of explosives and propellant components. They also offer experimental results examining factors such as subsurface decomposition, evaporation, and dispersion of materials, which can be used to control combustion of condensed systems.

Providing several approaches to stability, safety, and controlled combustion of flammable substances, Thermal Decomposition and Combustion of Explosives and Propellants is a multi-dimensional resource for graduate students, researchers and professionals interested in chemical kinetics, the combustion and synthesis of high-energy materials, criminal forensics, and the field of explosives, powders, and solid rocket propellants.INTRODUCTION KINETIC PROBLEMS OF DECOMPOSITION OF EXPLOSIVES AND PROPELLANTS
References

GENERAL REGULARITIES OF THERMAL DECOMPOSITION OF HIGH-ENERGY COMPOUNDS
Gas Phase Reactions
Liquid Phase Reactions
Decomposition In The Solid State
References

ALIPHATIC NITROCOMPOUNDS
Gas Phase Decomposition By The Molecular Mechanism
Gas Phase Decomposition By The Radical Mechanism
Competition Of The Radical And Molecular Mechanisms
Reactions In The Condenl3*