Grain boundaries are important structural components of polycrystalline materials used in the vast majority of technical applications. Because grain boundaries form a continuous network throughout such materials, their properties may limit their practical use. One of the serious phenomena which evoke these limitations is the grain boundary segregation of impurities. It results in the loss of grain boundary cohesion and consequently, in brittle fracture of the materials. The current book deals with fundamentals of grain boundary segregation in metallic materials and its relationship to the grain boundary structure, classification and other materials properties.This book deals with the fundamentals of grain boundary segregation in metallic materials and its relationship to the grain boundary structure, classification and other materials properties.Grain boundaries are important structural components of polycrystalline materials used in the vast majority of technical applications. Because grain boundaries form a continuous network throughout such materials, their properties may limit their practical use. One of the serious phenomena which evoke these limitations is the grain boundary segregation of impurities. It results in the loss of grain boundary cohesion and consequently, in brittle fracture of the materials. The current book deals with fundamentals of grain boundary segregation in metallic materials and its relationship to the grain boundary structure, classification and other materials properties.I. IntroductionII. Grain boundaries: structure, description and thermodynamicsIII. Approaches to Study Grain Boundary SegregationIV. Models of Equilibrium Grain Boundary SegregationV. Effect of Variables on Equilibrium Grain Boundary SegregationVI. Principles of Non-Equilibrium SegregationVII. Grain Boundary Segregation and Related Phenomena and metallurgical phenomenaVIII. Concluding remarksThe University of Bristol calls Lejcek 'an acknowledged expert in establishing lc