Inorganic Syntheses [Hardcover]

The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.Chapter One LIGANDS FOR WATER-SOLUBILIZING ORGANOMETALLIC COMPOUNDS.

1. (Meta-Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1).

2. Syntheses of Water-Soluble Phosphines and Their Transition Metal Complexes.

3. Tris[Tris(Sodium m-sulfonatophenyl)phosphino] Palladium(0)-Enneahydrate.

4. Sulfonated Phosphines.

5. (S,S)-2,3-Bis[Di(m-Sodiumsulfonatophenyl)phosphino]butane-(chiraphos_TS) and (S,S)-2,4-Bis[di(m-Sodiumsulfonatophenyl)-phosphinolpentane (BDPP_TS).

6. 1,3,5-Triaza-7-phosphatricyclo[3.3.1.1^3,7]decane and Derivatives.

Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS.

7. 2.2':6',2 -Terpyridine.

8. Poly(1-pyrazolyl)alkane Ligands.

9 . Tris[N-(3-tert-butyl)pyrazolyl]methane.

10. Tris[2-(1,4-Diisopropylimidazolyl)]phosphine.

11. Tris[(2-pyridyl)methyl]amine (TPA) and (+)-Bis[(2-pyridyl)-methyl]-l-(2-pyridyl)ethylamine (a-MeTPA).

12. C₂-Symmetric 1,4-Diisopropyl-7-R-l,4,7-Triazacyclononanes.

13. N-(2-hydroxyethyl)-3,5-Dimethylpyrazole, a Dinuclear Copper Complex, and N-(2-p-Toluenesulfonylethyl)-3,5-dimethlC