An Introduction to Hydrogen Bonding [Paperback]

Hydrogen bonds range from the very strong, comparable with covalent bonds, to the very weak, comparable with van der Waals forces. Most hydrogen bonds are weak attractions with a binding strength about one-tenth of that of a normal covalent bond. Nevertheless, they are very important. Without them, all wooden structures would collapse, cement would crumble, oceans would vaporize, and all living things would disintegrate into inanimate matter.
An easy-to-read supplement to the often brief descriptions of hydrogen bonding found in most undergraduate chemistry and molecular biology textbooks,An Introduction to Hydrogen Bondingdescribes and discusses the current ideas concerning hydrogen bonding, ranging from the very strong to the very weak, with introductions to the experimental and theoretical methods involved. Ideal for courses in chemistry and biochemistry, it will also be useful for structural biology and crystallography courses. For students and researchers interested in supramolecular chemistry, biological structure and recognition, and other sophisticated concepts and methodologies, it provides a careful selection of key references from the vast hydrogen bonding literature.

Preface
Chapter 1 BRIEF HISTORY
1.1. Introduction
1.2. Who Discovered the Hydrogen Bond and When?
1.3. Books on Hydrogen Bonding
Chapter 2 NATURE AND PROPERTIES
2.1. A Simple Criterion and Some Definitions
2.2. Different Categories
2.3. Insight from Theory
2.4. Charge Density Studies
2.5. Geometry in Crystals
2.6. The Vibrational Properties
2.7. Electrostatic Potentials
2.8. Hydrogen Bond Lengthsvs.van der Waals Radii Sums
2.9. What Makes the Hydrogen Bond Unique?
Chapter 3 STRONG HYDROGEN BONDS
3.1. Introduction
3.2. The Hydrogen Bifluoride Ion: a Prototype Strong Bond
3.3. Other H- - -F Bonds
3.4. O-H- - -O Bonds
3.5. O-H- - -O Hydrogen Bonds
3.6. ThlS4