Thermodynamics in Geochemistry The Equilibrium Model [Hardcover]

This textbook and reference outlines the fundamental principles of thermodynamics, emphasizing applications in geochemistry. The work is distinguished by its comprehensive, balanced coverage and its rigorous presentation. The authors bring years of teaching experience to the work, and have attempted to particularly address those areas where other texts on the subject have provided inadequate coverage. A thorough review of the necessary mathematics is presented early on, both as a refresher for those with a background in university calculus, and for the benefit of those coming to the subject for the first time. The text is written for students in advanced undergraduate or graduate-level geochemistry as well as for all researchers in this field.

1. Introduction
2. Mathematical Background
3. Introduction to Thermodynamic Terms
4. The First Law of Thermodynamics
5. The Second Law of Thermodynamics
6. Statistical Interpretation of Entropy
7. Thermodynamic Properties of Simple Systems -- Measurement, Calculation, and Presentation
8. Applications to Simple Systems
9. Partial and Apparent Molar Properties
10. Ideal Solution
11. Fugacity and Activity
12. Standard States
13. The Equilibrium Constant
14. Heterogeneous and Open Systems
15. Solid Solutions
16. Gaseous Solutions
17. Aqueous Electrolyte Solutions
18. Redox Systems
19. Speciation Calculations

Provides an innovative, careful, and complete development of the subtleties of thermodynamics that anyone seeking an understanding of phase equilibria in a wide variety of earth processes needs to grasp. . . . a cohesive treatise with well-explained examples. I imagine it will become the standard text for teaching the basics of thermodynamics as well as introducing more advanced models of solution theory. It will also likely become a classic reference for working scientists. --Science

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